mathematical modeling of single and multi-component adsorption fixed beds to rigorously predict the mass transfer zone and breakthrough curves

Authors

mohsen siahpoosh

shohreh fatemi

ali vatani

abstract

the aim of the present work is to prepare an adsorption package to simulate adsorption / desorption operation for both single and multi-component systems in an isothermal condition by different mechanisms such as; local adsorption theory and mass transfer resistance (rigorous and approximated methods). different mass transfer resistance mechanisms of pore, solid and bidispersed diffusion, together with nonlinear isotherms (longmuir, frendlich, sips and toth) are taken into account in modeling the fixed bed adsorbers. the extended longmuir isotherm was found to explain properly the binary and ternary mixtures in adsorption/desorption process.almost all the mass transfer approximations were explained by the linear driving force, ldf,  although the alternative driving force, adf, approximation was examined in some cases. the numerical solution was the implicit method of lines which converted the partial differential equations to the odes then solving them by the runge-kutta method. validation of the models was performed by the experimental data derived from the literature for different types of adsorbents and adsorbates. the sensitivity analyses was carried out to find out variation of the breakthrough curves against some physical and operational parameters such as; temperature, flow rate, initial and  inlet concentration and particle adsorbent size. the results revealed excellent agreement of simulated and previously published experimental data.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Mathematical Modeling of Single and Multi-Component Adsorption Fixed Beds to Rigorously Predict the Mass Transfer Zone and Breakthrough Curves

The aim of the present work is to prepare an adsorption package to simulate adsorption / desorption operation for both single and multi-component systems in an isothermal condition by different mechanisms such as; local adsorption theory and mass transfer resistance (rigorous and approximated methods). Different mass transfer resistance mechanisms of pore, solid and bidispersed diffusion, t...

full text

Mathematical Modeling of Fixed Bed Adsorption: Influence of Main Parameters on Breakthrough Curve

Dynamic modeling and simulation of fixed bed adsorption process was carried out by explaining the behavior of breakthrough curve parameter. Adsorption of sulfur compound, present in road fuel, has posed a great challenge. A model of fixed bed adsorption of benzothiophene from fuel was formulated with non-ideal plug flow behavior and considered velocity variation along a column. The model was so...

full text

investigation of single-user and multi-user detection methods in mc-cdma systems and comparison of their performances

در این پایان نامه به بررسی روش های آشکارسازی در سیستم های mc-cdma می پردازیم. با توجه به ماهیت آشکارسازی در این سیستم ها، تکنیک های آشکارسازی را می توان به دو دسته ی اصلی تقسیم نمود: آشکارسازی سیگنال ارسالی یک کاربر مطلوب بدون در نظر گرفتن اطلاعاتی در مورد سایر کاربران تداخل کننده که از آن ها به عنوان آشکارساز های تک کاربره یاد می شود و همچنین آشکارسازی سیگنال ارسالی همه ی کاربران فعال موجود در...

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

15 صفحه اول

the innovation of a statistical model to estimate dependable rainfall (dr) and develop it for determination and classification of drought and wet years of iran

آب حاصل از بارش منبع تأمین نیازهای بی شمار جانداران به ویژه انسان است و هرگونه کاهش در کم و کیف آن مستقیماً حیات موجودات زنده را تحت تأثیر منفی قرار می دهد. نوسان سال به سال بارش از ویژگی های اساسی و بسیار مهم بارش های سالانه ایران محسوب می شود که آثار زیان بار آن در تمام عرصه های اقتصادی، اجتماعی و حتی سیاسی- امنیتی به نحوی منعکس می شود. چون میزان آب ناشی از بارش یکی از مولفه های اصلی برنامه ...

15 صفحه اول

contribution of setting to the study of characters and the main idea in e. brontes: wuthering heights and t. hardys: return of the native.

this thesis aims to adduce an unmitigated and comprehensive explication concerning the relationship of three significant elements of fiction: setting, chracter and theme. my research is basically placed on two outstanding novels of the 19th century: emily brontes wuthering heights and thomas hardys return of the native. my endeavour lies in studying the correlation among the three above-mention...

15 صفحه اول

My Resources

Save resource for easier access later


Journal title:
iranian journal of chemistry and chemical engineering (ijcce)

Publisher: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

volume 28

issue 3 2009

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023